Výroba pevných biopaliv z vinného réví
Transkript
Výroba pevných biopaliv z vinného réví
Utilization of waste wood after vineyard pruning via production of solid bio-fuels O. Mužík1, J. Souček2, Z. Abrham1 1 Research Institute of Agricultural Engineering, Economy of Agricultural technological systems division, Drnovska 507, 16101 PRAHA, Czech Republic 2 Research Institute of Agricultural Engineering, Energy and logistics of technological systems and biomass utilization for non-food purposes division, Drnovska 507, 16101 PRAHA, Czech Republic [email protected], [email protected], [email protected] Summary This contribution is concerned about possibilities of the solid bio-fuels production from waste wood after the vineyard pruning. For the experiment the vine cane of four different varieties was used. The vine cane was chipped by the disc chipping machine PEZZOLATO – 110MB to the average particle size of 7 mm. After drying to 9.5 % moisture the chipped material from the vine cane was pressed in the form of cylindrical briquettes using the hydraulic press with solid pressing chamber Briklis HLS 70. Consequently the vine cane briquettes analysis and combustion test were carried out at the laboratories. The performed measurements have proved that the vine cane briquettes have comparable energy and mechanical properties as those from energy wood species produced in the identical devices. Key words: vine cane, chipping, briquetting, utilization of biomass. Introduction There do not exist much possibilities how to purposefully utilize the waste wood after the vineyard pruning (so called vine cane). Previously the most frequent method of vine cane processing was its removal from the inter row and consequent ineffective combustion. Besides atmosphere emission burden that method of liquidation is also at variance with the Act on Waste. Currently the most common is being exploited the vine cane crushing just at the inter row and left for consequent decay. Other option is its utilization as a raw material for solid biofuels production or as material for composting. Material and methods Vine cane production and properties In the Czech Republic there is currently registered more than 19,000 ha of vineyards of which some 16,000 ha in period of fertility. Quantity of vine cane production depends on variety, age and in particular on type of line (i.e. number of shrubs per 1 hectare). Average values are ranging in almost from 0.45 to 1.20 kg per 1 shrub, i.e. about 3.50 t.ha-1 in average. More accurate figures are given in table 1 where for medium line (ML) and high line (HL) is presented shrubs number per 1 ha (corresponding with plant spacing) and further the individual varieties are divided into those with lesser or higher wood production. Table 1. Waste wood production after vineyard pruning. Type of line Age [years] ML1 Number [pcs.ha-1] 15 Vine variety [kg.shrub-1] [t.ha-1] 0.45-0.50 2.0-3.2 Svg , PM 0.60-0.70 2.7-3.2 RV4, RB7, RŠ8 0.70-0.80 2.3-2.6 5 0.90-1.20 3.0-4.0 Tr3, RV4 4 500 5 HL2 13 3 300 6 9 Svg , Sv 1 2 3 4 Waste wood production 5 Average [t.ha-1] 3.05 3.50 6 medium line, high line, Tramín, Ryzlink vlašský, Sauvignon, Portugal modrý, 7Rulandské bílé, 8Rulandské šedé, Svatovavřinecké 9 The vine cane volume weight depends on moisture, at 30 –35 % it ranges between 250 - 350 kg.m-3. Production procedures and determination of vine cane briquettes properties For the experiment the vine cane of four different variants (MP3, Sv4, Vc5, MT6) was used in approximately equal ratio. Immediately on the day of harvest – end of February this year – the vine cane was chipped by the P chipper PEZZOLATO 110MB. The vine cane moisture was 63 % at the harvest period and the chipped material specific mass was 480 kg.m-3. The chipper performance and fuel consumption are presented in table 2. Table 2. Chipper PEZZOLATO 110MB performance and fuel consumption for vine chipping. Vine variety MP3, Sv4 Sv4, VČ5 MT6 A B C P 1 Time of chipping [min.] 25 20 25 Amount of chipped material1 [kg] 78 66 75 Efficiency of chipper 1 [kg.h-1] 187 196 180 Fuel consumption2 [l] 0,8 0,6 0,7 Converted to 10 % moisture Natural 95 3 Modrý Portugal 4 Svatovavřinecké 5 Veltlínské červené ranné 6 Müller Thurgau 2 To determine the chipped material granularity the screen analysis was carried out. Results of this analysis according to the standard ČSN ISO 9276-1 performed with the sheet sieves with round meshes are presented in table 3. The structure of chipped material is also shown in Figure 1. Table 3. Vine cane chipped material granularity according to standard ČSN ISO 9276-1 Particles size 31.5 22.4 16 11.2 8 7 6.3 5.5 5 4.5 4 3.5 2.8 2.5 xi [mm] Distribution density q3i 0.1 6.4 2 1.4 1 10.4 13.6 8.0 36.3 3.8 5.0 2.7 2.7 2.6 1.0 4.5 0.3 1.1 0.5 .05 Fall Sum down 0.6 100.0 [%] Figure 1. Chipped vine cane in press Briklis HLS 70. The chipped material was transported to the roofed facility without heating and stored there on the concrete floor in a heap of height about 0.5 m. In first two weeks of storage the heap was over-dug twice and then stored in loose form on the same surface. Within 3 mouths since end of February to end of May the chipped material gradually dried out from initial 63 % to 9.5 %. After that the vine cane chipped material of moisture 9.5 % was pressed in the form of cylindrical briquettes using press Briklis HLS 70. It is a hydraulic press equipped with solid pressing chamber. The preasure was set up at 450 kPa during the pressing process. The press performance and electricity consumption are listed in table 4. Table 4. Performance and electricity consumption of press Briklis HLS 70 during the vine cane briquettes pressing. A B C D Pressing time [min.] 20 20 20 15 Briquettes amount [kg] 17.6 18.0 18.1 14.4 Press performance [kg.h-1] 52.8 54.0 54.3 57.6 Electricity consumption [kWh] 0.8 0.8 0.8 0.6 E 15 13.7 54.8 0.6 Consequently the analysis of vine cane briquettes was carried out at laboratory of the Institute of Chemical Technology in Prague (ICT) where the briquettes basic energy properties were specified. Content of elements in material was determined by chromatography method. The combustion heat and heating value figures were determined by the standard ČSV ISO 1928 and ash content by the standard ČSN ISO 1171. The briquettes combustion test was conducted in the type combustion device (heat storage stove SK-2 RETAB 8 kW) at laboratory of the Research institute of Agricultural Engineering in Prague (RIAE). During this test emissions generated within the tested briquettes combustion were determined by the combustion products analyzer GA 60 MADUR. The combustion test was implemented in compliance with standard ČSN EN 13229 “In-built heating appliances and open fireplace insertions for solid fuels”. The average carbon monoxide concentration within the measurement as well as other gaseous emissions were converted to 13 % of oxygen content. By the mentioned standard the average carbon monoxide values have to fulfil the limit values for appropriate CO emission class as presented in table 5. Table 5. CO emission classes for local solid fuels appliances according to standard ČSN EN 13229. Appliance CO class 1 Class 1 Class 2 1mg.mN-3 = 0,0001 % Appliances with closed door Limit values of CO emissions classes (at 13 % O2) [% by volume] ≤ 0,31 > 0,3 ≤ 1,01 Results The vine cane briquettes density measured for 10 samples has ranged between 760 – 870 kg.m-3. Values above 1,000 kg.m-3 have not been reached for briquettes when pressed by the hydraulic press. Vine cane briquettes are documented with photographs in Figures 2 and 3. Figure 2. Pressing of the vine cane briquettes by press Briklis HLS 70. Figure 3. Vine cane briquettes pressed by press Briklis HLS 70. The obtained values are comparable with average figures of energy wood species of poplar or willow type when parameters are converted to dry matter. The ash content in the analyzed samples was slightly increased (3.46 %) but no one of them exceed value of 4.5 %. The vine cane briquettes analysis results as carried out at the laboratory of the ICT are presented in table 6. Table 6. Energy properties and chemical composition of vine cane briquettes. Indicator Moisture Volatile combustion matter Non-volatile combustion matter Ash C H N S O Cl Heat of combustion Heating value Ash softening point Ash melting point Ash flow point Unit % by weight % by weight % by weight % by weight % by weight % by weight % by weight % by weight % by weight % by weight MJ.kg-1 MJ.kg-1 °C °C °C Value 8.11 69.62 18.81 3.46 44.70 6.42 0.89 0.04 36.38 0.07 17.79 16.20 >1300 >1300 >1300 Results of combustion test are presented in table 7. Table 7. CO, CO2, NO and NO2 average concentrations in combustion of vine cane briquettes. Indicator CO CO2 NO NO2 NOx [mg.m-3] 6255.0 164.4 0.7 165.1 Values measured [mg.m-3 at 13% O2] 7073.5 185.9 0.8 186.7 [% by vol.] 0.50 6.06 0.01 0.01 Average concentration of the all investigated substances are in compliance with the technical standard ČSN EN 13229 values. Nevertheless the CO emissions have exceeded the permitted amount for class 1 but are in compliance with class 2 conditions with certain reserve. On contrary, the NOx emissions can be evaluated very positively. For the utilized combustion device the NOx limit value is not specified with regard to very low heat performance but according to the Directive No. 13-2002 of the Ministry of Environment of the Czech Republic specifying requirements for allocation of the trade mark “Ecologically Friendly Product” for hot water boiler for biomass combustion in the system of central heating up to 0.2 MW (Standards ČSN 07 02 40 and ČSN EN 3035) the NOx limit value is 250 mg.mN-3 at 11 % O2 and this value has not been exceeded. As mechanical and physical-mechanical properties regards the briquettes produced by the hydraulic press Briklis BHL 70 are comparable with those produced from the energy wood species pressed in the identical device. Conclusions Solid bio-fuels production from waste wood after vineyard pruning is an important possibility of vine cane energy utilization. At the RIAE conducted measurements have proved that the vine cane briquettes have comparable parameters with those from energy wood species experimentally produced in the identical devices. Despite some unsolved problems mainly of logistics and economical character it may be concluded that the vine cane energy utilization could become a perspective alternative of vine cane crushing and deposition just in the vineyard inter-row in accordance with still more severe legislation. Published results are part of research project NAZV 1G46082 “Technological systems and economy by integrated production of vegetable and grapevine”. 2007 References HUTLA, P., JEVIČ, P.: Porovnání emisních parametrů paliv na bázi rostlinných materiálů. In Zemědělská technika a biomasa 2006 : Sborník přednášek z mezinárodního semináře. Praha: VÚZT, 2005, S. 76-81. ISBN 86884-07-4 MUŽÍK, O., SCHEUFLER, V., PLÍVA, P., ROY, A: Kompostování vinného réví s travní hmotou. [Composting of vine cane with grass]. In Zemědělská technika a biomasa 2006 : Sborník přednášek z mezinárodního semináře s podporou MZe 21.11.2006, Praha. Praha : VÚZT, 2006, č. 4, s. 100–102. ISBN 80-86884-15-5 SLADKÝ, V., DVOŘÁK, J., ANDERT, D.: Obnovitelné zdroje energie – fytopaliva. Praha: VÚZT, 2002. ISBN 80-238-9952-X ŽUFÁNEK, J., ZEMÁNEK, P.: Bilance zdrojů biologických odpadů ve vinohradnictví a ovocnictví. Sborník mezinárodní vědecké konference „Ekologické aspekty výzkumu, vývoje a provozu zahradnické techniky“, Lednice 1998, str. 203 – 207. ISBN 80-7157-301-9
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